Vazo® free radical sources from DuPont provide efficient initiation of many chemical reactions, including:
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acrylic and vinyl polymerizations
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halogenations (brominations)
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oxidations and related chain reactions
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additions of small molecules across olefinic double bonds
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cross-linking
The DuPont™ Vazo® free radical sources are substituted azonitrile compounds that thermally decompose to generate two free radicals per molecule. (Nitrogen gas is also generated.) The rate of decomposition is first-order and is unaffected by contaminants such as metal ions.
Vazo® free radical sources are used to initiate bulk, solution, and suspension polymerizations. Vazo® products can be used alone, or in combination with other free radical initiators.